185145-45-3Relevant academic research and scientific papers
Tin-Pummerer rearrangement in the synthesis of O,S-acetal derivatives
Hatlelid, Jostein,Benneche, Tore,Undheim, Kjell
, p. 1092 - 1095 (2007/10/03)
α-Thioalkyl esters and carbonates have been prepared by a tin-Pummerer rearrangement in reactions of α-stannylated sulfoxides with acid chlorides or chloroformates, respectively. Acid chlorides have a higher reactivity than chloroformates in this reaction. Acta Chemica Scandinavica 1997.
Cleavage of carbon-sulfur bonds in the synthesis of α-haloalkyl carbonates
Hatlelid, Jostein,Benneche, Tore,Undheim, Kjell
, p. 1041 - 1044 (2007/10/03)
α-Chloroalkyl and α-bromoalkyl carbonates have been prepared by cleavage of α-arylthioalkyl carbonates with sulfuryl chloride or bromine, respectively. The α-arylthioalkyl carbonates are prepared by reaction of the hemithioacetal 1 with chloroformates or by a destannylative tin-Pummerer rearrangement of α-stannyl sulfoxides. Acta Chemica Scandinavica 1996.
