185197-80-2

Basic information

• Product Name: Ethanone, 1-(6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)-, (3R)-[partial]- (9CI)
• Synonyms: Ethanone, 1-(6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)-, (3R)-[partial]- (9CI)
• CAS NO: 185197-80-2
• Molecular Formula: C9H14O2
• Molecular Weight: 154.20626
• Product Categories: ACETYLGROUP
• Mol File: 185197-80-2.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Ethanone, 1-(6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)-, (3R)-[partial]- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)-, (3R)-[partial]- (9CI)(185197-80-2)
• EPA Substance Registry System: Ethanone, 1-(6-methyl-7-oxabicyclo[4.1.0]hept-3-yl)-, (3R)-[partial]- (9CI)(185197-80-2)

Safety Data

• Hazardous Substances Data: 185197-80-2(Hazardous Substances Data)

Upstream product

• 108-24-7 acetic anhydride 
• 1195-92-2 (4R)-limonene 1,2-epoxide 
• 5989-27-5 D-limonene 

Downstream Products

• 6090-09-1 methyl-[(1R)-4-methylcyclohex-3-enyl]ketone 

Relevant articles and documents

Stereoselective Palladium-Catalyzed Approach to Vitamin D3 Derivatives in Protic Medium

We describe an efficient convergent synthesis of vitamin D3 metabolites and analogues. The synthetic strategy relies on a tandem Pd-catalyzed A-ring closure and Suzuki–Miyaura coupling to the CD-side chain component to set directly the vitamin D triene system under protic conditions. This strategy enables rapid access to vitamin D3 and 3-epi-vitamin D3 metabolites and analogues modified at the side chain for biological evaluation and structural and metabolic studies.

Synthesis and absolute configuration of rotundial, a mosquito repellent from the leaves of vitex rotundiforia

The enantiomers of rotundial (1), a mosquito repellent from the leaves of Vitex rotundiforia, were synthesized from the enantiomers of limonene oxide (2). The absolute configuration of natural rotundial was determined to be R.