185245-92-5

Upstream product

• 882-33-7 diphenyldisulfane 
• 185245-91-4 N-tert-butoxycarbonyl-8,9-methylenedioxy-6-oxo-1,2,3,4,5,6-hexahydro-3-benzazocine 
• 112342-26-4 6,7-methylenedioxy-1-(Z)-(methoxycarbonyl)-methylidene-1,2,3,4-tetrahydroisoquinoline 
• 185245-90-3 N-tert-butoxycarbonyl-6-hydroxy-8,9-methylenedioxy-1,2,3,4,5,6-hexahydro-3-benzazocine 
• 157034-57-6 1,3,4,9b-Tetrahydro-2H-6,8-dioxa-2a-aza-cyclobuta[a]cyclopenta[g]naphthalene 2a-oxide 
• 185245-80-1 methyl 6,7-methylenedioxy-1,2,3,4-tetrahydroisoquinoline-1-acetate 
• 185245-78-7 7,8-methylenedioxy-1,4,5,9b-tetrahydro-2H-azeto<2,1-a>isoquinoline 
• 185245-88-9 8,9-methylenedioxy-1,2,5,6-tetrahydro-4H-3,6-epoxy-3-benzazocine 
• 185245-89-0 6-hydroxy-8,9-methylenedioxy-1,2,3,4,5,6-hexahydro-3-benzazocine 
• 185245-86-7 1-(2-hydroxyethyl)-6,7-methylenedioxy-1,2,3,4-tetrahydroisoquinoline 
• 185245-87-8 1-(chloroethyl)-6,7-methylenedioxy-1,2,3,4-tetrahydroisoquinoline 

Relevant academic research and scientific papers

An efficient synthesis of magallanesine using [1,2]-Meisenheimer rearrangement and Heck cyclization

A straightforward total synthesis of magallanesine 1 was accomplished from readily available isoquinolineacetate 14. This synthesis is emphasized by the following two points; i. the [1,2]-Meisenheimer rearrangement of the azetidine N-oxide 22 for the prep