185259-07-8Relevant academic research and scientific papers
Synthesis and crystal structures of η2-sulfenamido complexes of ruthenium and nickel, and of chromium imido and cobalt iminophosphorane complexes via sulfenamido rearrangement
Hankin, Danielle M.,Danopoulos, Andreas A.,Wilkinson, Geoffrey,Sweet, Tracy K. N.,Hursthouse, Michael B.
, p. 4063 - 4069 (2007/10/03)
The interaction of [Ru(η-C5Me5)Cl2]2 with Li(ButNSPh), gave two products, Ru(η4-C5Me4CH2)(η 2-ButNSPh)Cl 1 and the dimer Cl(η-C5Me5)Ru(μ-NBu t)(μ-SPh)Ru(η-C5Me5) 2; the former is best described as a η4-tetramethylfulvene ruthenium(II) complex, while in the latter the bridging tert-butylimido and benzenethiolato groups were formed by S-N cleavage of sulfenamido species. A similar cleavage resulted in the formation of CrV(η-C5Me5)(NBut)(SPh) 2 3, in the interaction of Li(ButNSPh) with [Cr(η-C5Me5)Br2]2. Interaction of CoCl2(PMe3)3 with Li(p-MeC6H4NSPh) gave the iminophosphorane complex Co(p-MeC6H4NPMe3)2(SPh)2 4. Interaction of NiCl2(PMe3)2 with Li(ButNSPh) gave Ni(η2-ButNSPh)2(PMe3) 5. The structures of compounds 1-5 have been confirmed by X-ray crystallography.
