18533-49-8Relevant academic research and scientific papers
A carbone-stabilized two-coordinate phosphorus(III)-centered dication
Tay, Madelyn Qin Yi,Lu, Yunpeng,Ganguly, Rakesh,Vidovic, Dragoslav
, p. 3132 - 3135 (2013)
A coordinatively unsaturated dicationic phosphorus compound has been synthesized and characterized (see structure; P pink, N blue, C gray). DFT calculations revealed that the polycation should show superior Lewis acid and σ-donor properties to the corresponding bis(dimethylamino)phosphenium cations. Preliminary investigations with PMe3 confirmed unusual reactivity patterns for the dication.
