185385-63-1Relevant academic research and scientific papers
Stereoselective total synthesis of nemorosone
Uwamori, Masahiro,Saito, Aya,Nakada, Masahisa
, p. 5098 - 5107 (2012)
The highly stereoselective total synthesis of nemorosone via a new approach to the bicyclo[3.3.1]nonane-2,4,9-trione core which features intramolecular cyclopropanation of an α-diazo ketone, stereoselective alkylation at the C8 position, and regioselectiv
Stereoselective total synthesis of garsubellin A
Uwamori, Masahiro,Nakada, Masahisa
, p. 141 - 145 (2013/08/25)
The stereoselective total synthesis of garsubellin A is described. The total synthesis was achieved through the stereoselective construction of a bicyclo3.3.1nonane derivative via a three-step sequence: intramolecular cyclopropanation, formation of a germ
Synthetic studies on phloroglucins: a new approach to the bicyclo[3.3.1]nonane system via the regioselective ring-opening of the methoxycyclopropane
Abe, Masahito,Nakada, Masahisa
, p. 4873 - 4877 (2008/02/05)
A new synthetic approach to the bicyclo[3.3.1]nonane system, a common structure in a number of polyisoprenylated phloroglucinol derivatives (phloroglucins), has been developed. The key step in our approach is a 'one-pot' procedure of two successive reacti
