185394-28-9

Upstream product

• 117556-90-8 (8aR)-3,4,8,8a-tetrahydro-8a-methyl-1,6(2H,7H)-naphthalenedione 1-ethylene ketal 
• 181137-05-3 C₁₃H₂₀O₃ 
• 181137-06-4 C₁₃H₂₂O₂ 
• 180912-70-3 (4aR,8aR)-8a-Methyl-1-methylene-decahydro-naphthalene 
• 185394-24-5 ((4aR,8aR)-8a-Methyl-decahydro-naphthalen-1-yl)-methanol 
• 59982-00-2 (+)-(9R,10R)-9-methyl-1-decalone 
• 100348-93-4 (R)-Wieland-Miescher ketone 
• 2033-89-8 3,4-dimethoxyphenol 
• 133129-56-3 1,2-dimethoxy-4-(methoxymethoxy)benzene 
• 180912-73-6 (4aR,8aR)-1-formyl-1,2,3,4,4a,5,6,7,8,8a-decahydro-8a-methylnaphthalene 

Downstream Products

• 180912-46-3 (1R,4aR,8aR)-1-(2,3-Dimethoxy-6-methoxymethoxy-benzyl)-8a-methyl-decahydro-naphthalene 

Relevant academic research and scientific papers

Synthesis of various model compounds for the central tricyclic ring system of popolophuanone E

An efficient synthesis of various model compounds 4a-e for the tricyclic core of popolophuanone E (1), a novel marine natural product, was accomplished; the method features highly regioselective annulation of the phenols 5a-e with the 2,3-dichloro-1,4-benzoquinones 7, 7c-e. Preliminary studies definitely demonstrated the feasibility of our designed synthetic strategy for 1 (the phenolic subunit I + the quinone subunit II → 1).