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185426-01-1

Formamide, N-[(1S,2R)-1-methyl-2-[(1R)-1-methyl-2-nitroethoxy]-2-phenylethyl]- is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 185426-01-1 Structure

  • Basic information

    1. Product Name: Formamide, N-[(1S,2R)-1-methyl-2-[(1R)-1-methyl-2-nitroethoxy]-2-phenylethyl]-
    2. Synonyms:
    3. CAS NO:185426-01-1
    4. Molecular Formula: C13H18N2O4
    5. Molecular Weight: 266.297
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 185426-01-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Formamide, N-[(1S,2R)-1-methyl-2-[(1R)-1-methyl-2-nitroethoxy]-2-phenylethyl]-(CAS DataBase Reference)
    10. NIST Chemistry Reference: Formamide, N-[(1S,2R)-1-methyl-2-[(1R)-1-methyl-2-nitroethoxy]-2-phenylethyl]-(185426-01-1)
    11. EPA Substance Registry System: Formamide, N-[(1S,2R)-1-methyl-2-[(1R)-1-methyl-2-nitroethoxy]-2-phenylethyl]-(185426-01-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 185426-01-1(Hazardous Substances Data)

185426-01-1 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 185426-01-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,5,4,2 and 6 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 185426-01:
(8*1)+(7*8)+(6*5)+(5*4)+(4*2)+(3*6)+(2*0)+(1*1)=141
141 % 10 = 1
So 185426-01-1 is a valid CAS Registry Number.

185426-01-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name (1S,2R,1'R)-(-)-N-<1-methyl-2-(1'-methyl-2'-nitroethoxy)-2-phenylethyl>formamide

1.2 Other means of identification

Product number -
Other names N-[(1S,2R)-1-Methyl-2-((R)-1-methyl-2-nitro-ethoxy)-2-phenyl-ethyl]-formamide

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:185426-01-1 SDS

185426-01-1Relevant articles and documents

Diastereo- and enantioselective synthesis of vicinal amino alcohols by oxa Michael addition of N-formylnorephedrine to nitro alkenes

Enders, Dieter,Haertwig, Andreas,Raabe, Gerhard,Runsink, Jan

, p. 1771 - 1792 (2007/10/03)

The first intermolecular asymmetric oxa Michael additions with removable chirality information within the hydroxide source are reported. As enantiopure oxygen nucleophile functioning as chiral hydroxide equivalent N-formylnorephedrine (7) was used and conjugate additions to aliphatic (E)-nitro alkenes 2a-j were carned out in good yields (35-87%) and excellent diastereomeric excesses (de = 94-≥98%). After reduction of the nitro group and protection of the amino function (11a-h, 73-87%, both steps), the cleavage of the auxiliary occurred without epimerisation (69-99%) using Na/NH3. The Boc-protected 2-amino alcohols 12a-h could be obtained in good overall yields (30-58 %, four steps) and excellent diastereomeric and enantiomeric excesses (de, ee = 94-≥98%). Transition states explaining the overall stereochemical outcome are presented based on the absolute configuration determined by X-ray structure analysis on 8b.

Enantioselektive Synthese von vicinalen Aminoalkoholen durch Oxa-Michael-Addition

Enders, Dieter,Haertwig, Andreas,Rabe, Gerhard,Runsink, Jan

, p. 2540 - 2542 (2007/10/03)

Keywords: Aminoalkohole; Asymmetrische Synthesen; Michael-Additionen; Nitroalkene; Synthesemethoden

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