Cas 185458-45-1,[Ti(OC6H5)2(C5H4Si(CH3)3)(C5H4CH2CH2N(C3H7)2)]

185458-45-1

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Product Name: [Ti(OC₆H₅)2(C₅H₄Si(CH₃)3)(C₅H₄CH₂CH₂N(C₃H₇)2)]
Synonyms:
CAS NO:185458-45-1
Molecular Formula:
Molecular Weight: 563.691
EINECS: N/A
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Chemical Properties

Melting Point: N/A
Boiling Point: N/A
Flash Point: N/A
Appearance: N/A
Density: N/A
Refractive Index: N/A
Storage Temp.: N/A
Solubility: N/A
CAS DataBase Reference: [Ti(OC₆H₅)2(C₅H₄Si(CH₃)3)(C₅H₄CH₂CH₂N(C₃H₇)2)](CAS DataBase Reference)
NIST Chemistry Reference: [Ti(OC₆H₅)2(C₅H₄Si(CH₃)3)(C₅H₄CH₂CH₂N(C₃H₇)2)](185458-45-1)
EPA Substance Registry System: [Ti(OC₆H₅)2(C₅H₄Si(CH₃)3)(C₅H₄CH₂CH₂N(C₃H₇)2)](185458-45-1)

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Hazardous Substances Data: 185458-45-1(Hazardous Substances Data)

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Check Digit Verification of cas no

The CAS Registry Mumber 185458-45-1 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,5,4,5 and 8 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 185458-45:
(8*1)+(7*8)+(6*5)+(5*4)+(4*5)+(3*8)+(2*4)+(1*5)=171
171 % 10 = 1
So 185458-45-1 is a valid CAS Registry Number.

185458-45-1Upstream product

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185458-45-1Relevant academic research and scientific papers

Mixed bent sandwich titanium complexes with the [2-(diisopropylamino)ethyl]cyclopentadienyl ligand - catalysts for the polymerization of ethylene and the dehydrocoupling of phenylsilane

Jutzi, Peter,Redeker, Thomas,Neumann, Beate,Stammler, Hans-Georg

, p. 1509 - 1515 (2007/10/03)

Mixed bent sandwich titanium(IV) complexes containing the donor-substituted [2-{diisopropylamino)ethyl]cyclopentadienyl (C5H4CH2CH2NjPr2 = CpN) ligand are described. The highly moisture-sensitive metallocene dichloride (C5H4CH2CH2NN;Pr2)(C 5H4SiMe3)TiCl2 (1) was synthesized by reaction of CpNLi with CpSTiCl3 (CpS ≡ C5H4SiMe3). Complex 1 reacts with one equivalent of HC1 with protonation of the amino group to give the air- and water-stable metallocene dichloride-hydrochloride [(C5H4CH2CH2-N(H)/Pr 2)(C5H4SiMe3)TiCl2] + Cl- (2). The structure of 2 was determined by a single-crystal X-ray diffraction study. Com-pounds 1 and 2 are precursors for ethylene polymerization catalysts. The reaction of 2 with one equivalent of Na+B[3,5-(CF3)2C6H3] 4- afforded the borate [(C5H4CH2CH2N(H)jPr 2)-{C5H4SiMe3)TiCl 2rB[3,5-(CF3)2C6H3] 4- (3). The dimethyl compound (C5H4CM2CH2NJPr2)(C 5H4SiMe3)TiMe2 (4) was obtained by reaction of 1 with two equivalents of methyllithium. The diphenoxy complex (C5H4CH2CH2-N/Pr2 2)(C5H4SiMe3)Ti(OPh)2 (5) was prepared analogously with a stoichiometric amount of lithium phenoxide. Compounds 4 and 5 show remarkable activity in the catalytic dehydrocoupling of phenylsilane. VCH Verlagsgesellschaft mbH, 1996.

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