185519-99-7Relevant academic research and scientific papers
Synthesis and Characterization of Gold(I) Complexes with the Ligand 1,2-Dithiolate-o-carborane. Crystal Structures of [Au2(μ-S2C2B10H10)(PPh3)2], [Au2(μ-S2C2B10H10)(μ-{(PPh2)2(CH=CH)})], and [Au2(μ-S2C2B10H10)(μ-{(PPh2)2(C6H4)})]
Crespo, Olga,Gimeno, M. Concepcion,Jones, Peter G.,Ahrens, Birte,Laguna, Antonio
, p. 495 - 500 (2008/10/09)
Treatment of 1,2-dimercapto-o-carborane with 2 equiv of [AuClL] in the presence of Na2CO3 gave the dinuclear complexes [Au2(μ-S2C2B10H10)L2] [L = PPh3 (1), PPh2Me (2), PPh2(C6H4Me-4) (3), SPPh3 (4)] where the dithiolate ligand bridges both gold atoms. Fur
