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185536-01-0

(1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • (1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester

    Cas No: 185536-01-0

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  • (1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester

    Cas No: 185536-01-0

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  • Shanghai Scochem Technology Co., Ltd.
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  • 185536-01-0 Structure

  • Basic information

    1. Product Name: (1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester
    2. Synonyms: (1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester
    3. CAS NO:185536-01-0
    4. Molecular Formula:
    5. Molecular Weight: 758.86
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 185536-01-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: (1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester(CAS DataBase Reference)
    10. NIST Chemistry Reference: (1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester(185536-01-0)
    11. EPA Substance Registry System: (1S,4S,5R,6R,7R)-4,7-Diacetoxy-1-((4S,5R)-4-acetoxy-5-methyl-3-methylene-6-phenyl-hexyl)-6-((E)-(4S,6S)-4,6-dimethyl-oct-2-enoyloxy)-2,8-dioxa-bicyclo[3.2.1]octane-4,5-dicarboxylic acid dimethyl ester(185536-01-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 185536-01-0(Hazardous Substances Data)

185536-01-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 185536-01-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,8,5,5,3 and 6 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 185536-01:
(8*1)+(7*8)+(6*5)+(5*5)+(4*3)+(3*6)+(2*0)+(1*1)=150
150 % 10 = 0
So 185536-01-0 is a valid CAS Registry Number.

185536-01-0Upstream product

185536-01-0Downstream Products

185536-01-0Relevant articles and documents

Novel squalestatin derivatives arising from reactions at the allylic centre of the C1-side chain

Procopiou, Panayiotis A.,Dymock, Brian W.,Inglis, Graham G. A.,Lester, Michael G.,Roberts, Andrew D.,Sidebottom, Philip J.,Spooner, Stephen J.,Srikantha, Anton R. P.,Watson, Nigel S.

, p. 327 - 334 (1998)

Reaction of 2 with Ac2O-TMSOTf gives the triacetate 5, which on further reaction gives isomer 6, arising from an allylic rearrangement, whereas reaction of 2 with Et3SiH-TMSOTf gives tricycle 7 arising from addition of the C7-OH to the allylic centre. Attempted ionic reduction of triacetate 5 gives benzocycloheptene 8, arising from Friedel-Crafts alkylation of the phenyl ring by the allylic centre. Similar alkylation has been obtained with analogue 9, and with the trifluoromethanesulfonate ester of the allylic alcohol 13. Attempted ionic reduction of 17, lacking the allylic centre, gives 20 arising from ester hydrolysis at C4.

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