185897-11-4

Basic information

• Product Name: (2-{(2-{Bis-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-phenyl)-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-ethyl)-phosphonic acid dimethyl ester
• CAS NO: 185897-11-4
• Molecular Weight: 686.427
• Mol File: 185897-11-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2-{(2-{Bis-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-phenyl)-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-ethyl)-phosphonic acid dimethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2-{(2-{Bis-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-phenyl)-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-ethyl)-phosphonic acid dimethyl ester(185897-11-4)
• EPA Substance Registry System: (2-{(2-{Bis-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-phenyl)-[2-(dimethoxy-phosphoryl)-ethyl]-phosphanyl}-ethyl)-phosphonic acid dimethyl ester(185897-11-4)

Safety Data

• Hazardous Substances Data: 185897-11-4(Hazardous Substances Data)

Upstream product

• 4645-32-3 dimethylvinylphosphonate 
• 80510-04-9 1,2-bis(phosphino)benzene 

Relevant articles and documents

Synthesis and characterization of dioxorhenium complexes derived from water-soluble diphosphine tetraphosphonates

Water-soluble diphosphine tetraphosphonates [(RO)2OPCH2CH2]2P-X-P[CH 2CH2PO(OR)2]2 (X = C6H4 or C2H4, R = Et or Me) were synthesized in near-quantitative yields by a base-catalysed Michael addition of appropriate P-H bonded compounds to vinylphosphonates in the presence of potassium tert-butoxide. The reactions of these compounds with [ReO2I(PPh3)2] in biphasic media (aqueous-organic) produced water-soluble dioxorhenium complexes of the type [ReO2{[(RO)2OPCH2CH2] 2P-X-P(CH2CH2PO(OR)2] 2}2]+ in nearquantitative yields. The water-soluble phosphines and their rhenium complexes were characterized by IR, 1H and 31P NMR and high-resolution fast atom bombardment mass spectral analysis.