185899-64-3Relevant academic research and scientific papers
Copper-Catalyzed Dehydrogenative Diels-Alder Reaction
Jiang, Bing,Liang, Qiu-Ju,Han, Yu,Zhao, Meng,Xu, Yun-He,Loh, Teck-Peng
, p. 3215 - 3219 (2018/06/11)
A practical and effective copper-catalyzed dehydrogenative Diels-Alder reaction of gem-diesters and ketone with dienes has been established. The active dienophiles were generated in situ via a radical-based dehydrogenation process, which reacted with a wide variety of dienes to afford various polysubstituted cyclohexene derivatives in good to excellent yields.
3-aza[5]metacyclophanes: Synthesis and reactions
Van Es, Daniel S.,Van Eis, Maurice J.,N'krumah, Stephen,Gret, Norbert,Egberts, Arnet,De Rijke, Marianne,De Kanter, Franciscus J.J.,De Wolf, Willem H.,Bickelhaupt, Friedrich,Spek, Anthony L.
, p. 799 - 824 (2007/10/03)
The synthesis of the dichloro substituted 3-aza[5]metacyclophane (6b) has been achieved starting from the N-tosyl derivative (7) by a four-step procedure consisting of dichlorocarbene addition, flash vacuum thermolysis, a second dichlorocarbene addition,
