1859-08-1

Basic information

• Product Name: ETHYL-D5 ALCOHOL
• Synonyms: ETHYL-D5 ALCOHOL;ETHYL-D5 ALCOHOL, 99.5 ATOM % D;ethanol-1,1,2,2,2-d5;Ethanol-d5;Alcohol-d5;Alcohol-d5 Anhydrous;Algrain-d5;Anhydrol-d5
• CAS NO: 1859-08-1
• Molecular Formula: C₂H₆O
• Molecular Weight: 51.1
• Product Categories: Aliphatics;Intermediates & Fine Chemicals;Pharmaceuticals
• Mol File: 1859-08-1.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 78-79 °C(lit.)
• Flash Point: 48 °F
• Appearance: /
• Density: 0.871 g/mL at 25 °C(lit.)
• Vapor Pressure: 82.8mmHg at 25°C
• Refractive Index: n20/D 1.358(lit.)
• CAS DataBase Reference: ETHYL-D5 ALCOHOL(CAS DataBase Reference)
• NIST Chemistry Reference: ETHYL-D5 ALCOHOL(1859-08-1)
• EPA Substance Registry System: ETHYL-D5 ALCOHOL(1859-08-1)

Safety Data

• Hazard Codes: F,T
• Statements: 11-20/22-36/37/38
• Safety Statements: 7-16-23-33-36/37/39-45
• RIDADR: UN 1170 3/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 1859-08-1(Hazardous Substances Data)

Usage

Uses

Most ethyl alcohol(Ethanol-d5) is used in alcoholic beverages in suitable dilutions. Other uses are as solvent in laboratory and industry , in the manufacture of denatured alcohol, pharmaceuticals, in perfumery, in organic synthesis. Used as antiseptic.

General Description

Ethanol-1,1,2,2,2-d5 (ethyl-d5 alcohol, CD3CD2OH) is deuterated ethyl alcohol. The nuclear magnetic relaxation rates of 13C in 13CCl4 and CD3CD2OH solvent mixture has been determined. The quantification of ethyl-d5 alcohol along with ethyl alcohol in serum by stable isotope gas chromatography-mass spectrometry technique has been reported. It plays a role as a tracer in the time-of-flight secondary ion mass spectrometry (TOF-SIMS) tracer method to assess the boundary lubricating behaviors of boundary lubricating films.

InChI:InChI=1/C2H6O/c1-2-3/h3H,2H2,1H3/i1D3,2D2

Upstream product

• 1112-02-3 d⁽³⁾-acetic acid 
• 64-17-5 ethanol 
• 74-93-1 methylthiol 
• 76453-09-3 <2H₅>ethyl nitrite 

Downstream Products

• 2679-89-2 bis-pentadeuterioethyl ether 
• 1617525-40-2 C₁₆H₂₁⁽²⁾H₅O₂ 
• 455264-31-0 zaurategrast 
• 59034-23-0 4-methylbenzenesulfonic acid [D₅]ethyl ester 
• 19199-91-8 chloro-pentadeuterio-ethane 
• 1632-89-9 acetaldehyde-d4 

Relevant articles and documents

Regioselective deuteration of alcohols in D2O catalysed by homogeneous manganese and iron pincer complexes

We report a convenient and cost-effective protocol for the regioselective deuteration of primary and secondary alcohols using Earth abundant homogeneous first row transition metal pincer catalysts. D2O is utilized as both a deuterium source and a solvent, allowing for a benign inexpensive process. Depending on the metal selected (Mn or Fe), a high degree of deuterium incorporation was observed selectively either at the α and β position (Mn) or exclusively at the α position (Fe), for primary alcohols. This simple, efficient, and cost-effective protocol for alcohol C-H bond deuteration constitutes a powerful tool for the large scale synthesis of deuterated molecules.

Conformational Equilibria of Pentane, Hexane, and Heptane

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