18617-42-0

Upstream product

• 2578-45-2 2-chloro-3,5-dinitropyridine 
• 62-53-3 aniline 
• 84249-28-5 2-phenoxy-3,5-dinitropyridine 
• 18617-41-9 2-Ethoxy-3,5-dinitro-pyridin 

Relevant academic research and scientific papers

Solvent effects on kinetics of the reaction between 2-chloro-3,5- dinitropyridine and aniline in aqueous and alcoholic solutions of [bmim]BF 4

Rate constants, kA. for the aromatic nucleophilic substitution reaction of 2-chloro-3,5-dinitropyridine with aniline were determined in different compositions of 1-(1-butyl)-3-methylimidazolium terafluoroborate ([bmim]BF4) mixed with

Solvent effects on kinetics of an heteroatomic nucleophilic substitution reaction in ionic liquid and molecular solvents mixtures

Rate constants, k A, for the aromatic nucleophilic substitution reaction of 2-chloro-3,5-dinitropyridine with aniline were determined in different compositions of 2-propanol mixed with hexane, benzene, and 2-methylpropan-2-ol and 1-ethyl-3-meth

Oxoiron(IV) Porphyrins Derived from Charged Iron(III) Tetraarylporphyrins and Chemical Oxidants in Aqueous and Methanolic Solutions

The oxidation of six charged iron(III) tetraarylporphyrins with chemical oxidants has been investigated.In aqueous solution each can be converted by tert-butyl hydroperoxide or monopersulphate into its corresponding oxoiron(IV) porphyrin, whereas in metha

The reaction of 2-phenoxy-3,5-dinitropyridine with substituted anilines in the presence of 1,4-diazabicyclo[2.2.2]octane in dimethyl sulfoxide: Kinetic and equilibrium studies

The reactions of 2-phenoxy-3,5-dinitropyridine (1) with, a series of substituted anilines (4a-d) in dimethyl sulfoxide (DMSO) in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) yield the 2-anilino derivatives without the accumulation of intermediate

Kinetic and equilibrium studies of σ-adduct formation and nucleophilic substitution in the reactions of 2-chloro-3,5-dinitropyridine and 2-ethoxy-3,5-dinitropyridine with p-substituted anilines in DMSO

Rate and equilibrium results for the reactions of 2-chloro-3,5- dinitropyridine and 2-ethoxy-3,5-dinitropyridine with a series of p-substituted anilines in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) were studied in DMSO. The reactions yielded 2

Solvent hydrogen bonding and structural effects on reaction of 2-chloro-3,5-dinitropyridine with para-substituted anilines in dimethylformamide/acetonitrile mixtures

Substitution reactions of some para-substituted anilines with 2-chloro-3,5-dinitropyridine were carried out conductometrically in dimethylformamide/acetonitrile mixtures. The rate data correlate poorly with macroscopic solvent parameters while excellently

Kinetics of the reaction of 2-chloro-3,5-dinitropyridine with meta- And para-substituted anilines in methanol

The kinetics of the reaction of 2-chloro-3,5-dinitropyridine (1) with meta- and para-substituted anilines (2a-j) to give 2-anilino-3,5-dinitropyridine derivatives (3a-j) were studied in methanol at different temperatures. IR studies of the products (3a-j)

The Effect of ortho Substituents on the Mechanism of Aromatic Nucleophilic Substitution Reactions in Dipolar Aprotic Solvents

The reactions of 2,6-dinitrophenyl phenyl ether and of 6-methyl-2,4-dinitrophenyl phenyl ether with piperidine, morpholine, butylamine and benzylamine are base catalysed in both dimethyl sulfoxide and acetonitrile.The reaction of 2-phenoxy-3,5-dinitropyridine with aniline is base catalysed in acetonitrile, but not in dimethyl sulfoxide, and its reactions with piperidine, morpholine, butylamine and benzylamine in acetonitrile are also base catalysed.The results are discussed in terms of the prevailing theories of aromatic nucleophilic substitution reactions.Increasein activation of the substrate increases the k2/k-1 and k3/k-1 ratios.For ortho substituents, steric/stereoelectronic effects in the transition state reduce both k-1, the rate constant for the decomposition of the zwitterionic intermediate to reactants, and k2 and k3, the rate constants for its decomposition to products.When the substrate has two ortho groups the different behaviour of primary and secondary amines found with substrates containing only one ortho-nitro group is not observed.

The Mechanisms of Nucleophilic Substitution Reactions of Aromatic Ethers with Amines in Benzene

The variation of the second-order rate constants with nucleophile concentration has been determined for the following reactions of some aromatic ethers with primary and secondary amines in benzene: 6-methyl-2,4-dinitrophenyl- and 2,6-dinitrophenyl phenyl