18635-73-9

Basic information

• Product Name: L-Alanine, N-(5,5-dimethyl-3-oxo-1-cyclohexen-1-yl)-, methyl ester
• CAS NO: 18635-73-9
• Molecular Formula: C12H19NO3
• Molecular Weight: 225.288
• Mol File: 18635-73-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: L-Alanine, N-(5,5-dimethyl-3-oxo-1-cyclohexen-1-yl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: L-Alanine, N-(5,5-dimethyl-3-oxo-1-cyclohexen-1-yl)-, methyl ester(18635-73-9)
• EPA Substance Registry System: L-Alanine, N-(5,5-dimethyl-3-oxo-1-cyclohexen-1-yl)-, methyl ester(18635-73-9)

Safety Data

• Hazardous Substances Data: 18635-73-9(Hazardous Substances Data)

Upstream product

• 13515-97-4 methyl 2-aminopropanoate monohydrochloride 
• 126-81-8 dimedone 

Downstream Products

• 137957-32-5 N-(2-Benzoyloxy-5,5-dimethyl-cyclohex-2-en-1-on-3-yl)-alanin-methylester 
• 137957-35-8 N-(6-Benzoyloxy-5,5-dimethyl-cyclohexa-2,5-dien-1-on-2-yl)-alanin-methylester 
• 137957-26-7 2-(2-Bromo-5,5-dimethyl-3-oxo-cyclohex-1-enylamino)-propionic acid methyl ester 
• 137957-31-4 N-(2,6-Dibrom-5,5-dimethyl-cyclohex-2-en-1-on-3-yl)-alanin-methylester 
• 137957-30-3 N-(2,4-Dibrom-5,5-dimethyl-cyclohex-2-en-1-on-3-yl)-alanin-methylester 
• 137957-24-5 N-(2-Chlor-5,5-dimethyl-cyclohex-2-en-1-on-3-yl)-alanin-methylester 

Relevant articles and documents

Halogenation and Acyloxylation of N-Cyclohex-2-en-1-on-3-yl-amino Acids

Secondary enaminones 2 are easily halogenated to yield the so far unknown halogenides 3, 4 and 5.Acyloxylation of enaminones 2 by dibenzoylperoxide leads to benzoyloxylated substances 13, which also have not been described yet.Bisacylated products could not be traced.Only the rearranged compounds 14 could be isolated. 14b showed cytotoxic activity. Keywords: Acyloxylations, Enaminones (sec.)