186382-61-6

Basic information

• Product Name: Acetic acid (1S,2S,3S,4R,5S,6R)-2,3-bis-benzyloxy-4,5-dihydroxy-6-methoxy-cyclohexyl ester
• Synonyms: Acetic acid (1S,2S,3S,4R,5S,6R)-2,3-bis-benzyloxy-4,5-dihydroxy-6-methoxy-cyclohexyl ester
• CAS NO: 186382-61-6
• Molecular Weight: 416.471
• Mol File: 186382-61-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid (1S,2S,3S,4R,5S,6R)-2,3-bis-benzyloxy-4,5-dihydroxy-6-methoxy-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (1S,2S,3S,4R,5S,6R)-2,3-bis-benzyloxy-4,5-dihydroxy-6-methoxy-cyclohexyl ester(186382-61-6)
• EPA Substance Registry System: Acetic acid (1S,2S,3S,4R,5S,6R)-2,3-bis-benzyloxy-4,5-dihydroxy-6-methoxy-cyclohexyl ester(186382-61-6)

Safety Data

• Hazardous Substances Data: 186382-61-6(Hazardous Substances Data)

Upstream product

• 186382-59-2 1D-(1,2,3,4)-1,2-di-O-benzyl-4-O-methylcyclohex-5-ene-1,2,3,4-tetraol 
• 10534-59-5 tetrabutylammonium acetate 
• 186382-60-5 Trifluoro-methanesulfonic acid (1R,2S,3S,4R,5S,6R)-2,3-bis-benzyloxy-4,5-dihydroxy-6-methoxy-cyclohexyl ester 

Downstream Products

• 10284-63-6 pinitol 
• 186388-12-5 (1R,2S,3R,4S,5R,6S)-5,6-Bis-benzyloxy-3-methoxy-cyclohexane-1,2,4-triol 

Relevant articles and documents

Total synthesis of (+)-pinitol

A new synthesis of (+)-pinitol 9 has been developed starting from the 7-oxanorbornenic sulfone (+)-5, prepared in enantiomerically pure form by resolution of the sulfonyl-7-oxanorbornanol 4. These precursors are available from the Diels-Alder adduct of furan and trans-1,2-bis-(phenylsulfonyl)-ethylene.