1864-99-9Relevant academic research and scientific papers
An expedient synthesis of ellipticine via Suzuki-Miyaura coupling
Konakahara, Takeo,Kiran,Okuno, Yuri,Ikeda, Reiko,Sakai, Norio
, p. 2335 - 2338 (2010)
A simple and efficient total synthesis of ellipticine was developed via the Suzuki-Miyaura coupling of sterically sensitive 2-hydroxybenzeneboronic acid with a multifunctional aryl halide using Pd(OAc)2 as a catalyst and Cu(OAc)2·H2O as an additive in DMSO/H2O as a key step followed by double N-arylation and cyclization.
Process for preparing an aryl formate and an aromatic carboxylic acid
-
Page 10, (2008/06/13)
A method of producing aryl formate by oxidizing the aromatic aldehyde in an organic solvent having substantially no ability of dissolving water with performic acid generated in situ in the reaction system from the reaction between formic acid and hydrogen peroxide. Optionally the method comprises a second step for decomposing the aryl formate to a phenol compound. This second step may be performed by thermally decomposing the aryl formate to the phenol compound and carbon monoxide at 110 to 350°C in liquid phase in the presence of an alkali metal compound.
