18641-46-8Relevant academic research and scientific papers
Transformation of RN=CHPh to R(R′3Si)NCH2Ph in the catalytic desulfurization of secondary thioamide with R′3SiH promoted by an iron complex
Fukumoto, Kozo,Sakai, Akane,Murai, Toshiaki,Nakazawa, Hiroshi
, p. 607 - 611 (2015/02/19)
The reaction of imine (RN=CHPh) with hydrosilane (R′3SiH) in the presence of CpFe(CO)2Me (1) revealed the formation of a hydrosilylation product (R(R′3Si)NCH2Ph). The findings helped us to understand the reaction mechanism of desulfurization of secondary thioamide catalyzed by 1 to give the corresponding imine and amine as a major and minor product, respectively.
Iridium(I)-catalysed tandem hydrosilylation-protodesilylation of imines
Field, Leslie D.,Messerle, Barbara A.,Rumble, Sarah L.
, p. 2881 - 2883 (2007/10/03)
In the presence of alkylsilanes, the cationic IrI complex [{Ir[bis(pyrazol-1-yl)methane](CO)2}BPh4] (1) catalyses the reduction of a range of imines, including N-alkyl and N-aryl imines, and both aldimines and ketimines. Excellent conversions directly to the product amines are achieved rapidly at room temperature in methanol solution. Wiley-VCH Verlag GmbH & Co. KGaA, 2005.
