186429-33-4

Upstream product

• 186581-53-3 diazomethane 
• 186429-32-3 (1R,3S,4S,5S,6S)-3-(tert-Butyl-diphenyl-silanyloxymethyl)-4-methoxycarbonylmethyl-6-vinyl-2-aza-bicyclo[3.1.0]hexane-2-carboxylic acid tert-butyl ester 
• 186429-20-9 (S,E)-methyl 4-((tert-butoxycarbonyl)amino)-5-((tert-butyldiphenylsilyl)oxy)pent-2-enoate 
• 186429-29-8 (E)-(S)-5-(tert-Butyl-diphenyl-silanyloxy)-4-((E)-penta-2,4-dienoylamino)-pent-2-enoic acid methyl ester 
• 24424-99-5 di-tert-butyl dicarbonate 

Relevant academic research and scientific papers

The synthesis of 4,5-methano congeners of α-kainic and α-allo-kainic acids as probes for glutamate receptors

The synthesis of diastereomeric 4,5-methano-L-proline 3-acetic acids is described starting from D-serine. The key reactions include a free-radical carbocyclization and an acid-catalyzed destannylative cyclopropanation of an iminium ion intermediate. Copyright (C) 1996 Elsevier Science Ltd.