186495-03-4

Basic information

• Product Name: Pt(P(C₆H₅)3)2(CH₂C(CH₃)COOC(CH₃)3)
• CAS NO: 186495-03-4
• Molecular Weight: 861.86
• Mol File: 186495-03-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pt(P(C₆H₅)3)2(CH₂C(CH₃)COOC(CH₃)3)(CAS DataBase Reference)
• NIST Chemistry Reference: Pt(P(C₆H₅)3)2(CH₂C(CH₃)COOC(CH₃)3)(186495-03-4)
• EPA Substance Registry System: Pt(P(C₆H₅)3)2(CH₂C(CH₃)COOC(CH₃)3)(186495-03-4)

Safety Data

• Hazardous Substances Data: 186495-03-4(Hazardous Substances Data)

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 585-07-9 tert-Butyl methacrylate 

Relevant articles and documents

Synthesis and characterisation of platinum(0) complexes of propenoates: X-ray diffraction study of [Pt(CH2=CHCO2CH2Ph)(PPh3)2]

Reaction of [Pt(C2H4)(PPh3)2] with propenoate or 2-methylpropenoate esters gave the complexes [Pt(propenoate)(PPh3)2] in good yield. These have been characterised by 1H, 13C, 31P and 195Pt NMR spectroscopy. The complex of benzyl propenoate has been characterised in a diffraction study. Reaction of the complexes produced with tricyclohexylphosphine, PCy3, gave [Pt(propenoate)(PCy3)(PPh3)]. The propenoate complexes were shown to be more stable than those of the 2-methylpropenoates.