1865-12-9Relevant articles and documents
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Kaye et al.
, p. 403,406 (1952)
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Enhanced Hydride Donation Achieved Molybdenum Catalyzed Direct N-Alkylation of Anilines or Nitroarenes with Alcohols: From Computational Design to Experiment
Huang, Ming,Huang, Yong-Liang,Ke, Zhuofeng,Lan, Xiao-Bing,Li, Weikang,Liu, Jiahao,Liu, Yan,Ye, Zongren,Zhao, Cunyuan
, p. 10377 - 10382 (2021/08/31)
An example of homogeneous Mo-catalyzed direct N-alkylation of anilines or nitroarenes with alcohols is presented. The DFT aimed design suggested the easily accessible bis-NHC-Mo(0) complex features a strong hydride-donating ability, achieving effective N-alkylation of anilines or challenging nitroarenes with alcohols. The enhanced hydride-donating strategy should be useful in designing highly active systems for borrowing hydrogen transformations.
Iron-catalysed hydroboration of non-activated imines and nitriles: Kinetic and mechanistic studies
Bazkiaei, Adineh Rezaei,Wiseman, Michael,Findlater, Michael
, p. 15284 - 15289 (2021/05/19)
Iron-catalysed hydroboration of imines and nitriles has been developed under low catalyst loading (1 mol%) in the presence of HBpin. A wide scope of substrate was found to smoothly undergo hydroboration, including electron releasing/withdrawing and haloge
Iodine-mediated 1,2-aryl migration of primary benzhydryl amines
Chang, Junbiao,Du, Yangxu,Hao, Wei,Hou, Jiao,Lu, Qing,Yu, Wenquan
supporting information, p. 16223 - 16226 (2021/09/22)
An iodine-mediated 1,2-aryl migration reaction of primary benzhydryl amines under transition metal-free conditions has been achieved. The crude imines generated by this rearrangement reaction can be directly transformed into various aromatic secondary ami
