186502-96-5Relevant academic research and scientific papers
Synthesis and reactivity of N-diphenylphosphinoyltroponimine: Synthetic entry into 1-azaazulene derivatives
Takayasu, Tohru,Ito, Koji,Nitta, Makoto
, p. 2667 - 2677 (2007/10/03)
A novel N-diphenylphosphinoyltroponimine (5), which is highly polarized and has a low lying LUMO, was prepared. The attempted reaction of 5 with enolate ions and enamines derived from cyclic ketones gave 1-azaazulene derivatives, albeit in low yields.
