186535-64-8Relevant academic research and scientific papers
Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide
Brask, Justin K.,Dura-Vila, Victor,Diaconescu, Paula L.,Cummins, Christopher C.
, p. 902 - 903 (2002)
A dramatic difference in behavior is observed for the dithiocarbamate and carbamate complexes [Ar(Butt)N]3V(NCE2)Na(THF)2(E = S or O, respectively), prepared from the corresponding nitride species {[Ar(Butt)N]3V≡NNa}2 by way of a nucleophilic addition reaction involving carbon disulfide or dioxide, and is rationalized with the aid of DFT calculations.
