186552-83-0Relevant academic research and scientific papers
Synthesis and characterization of long-chain ω-functionalized alkyl cobaloxime complexes
Starr, Earl J.,Naidoo, Morgan,Hutton, Alan T.,Moss, John R.
, p. 321 - 327 (1996)
Two new series of cobaloxime complexes of formulae [Co(Hdmg)2{(CH2)n I}(py)] (Hdmg = the monoanion of dimethylglyoxime, py = pyridine and n = 5, 6, 8, 9 or 10) and [Co(Hdmg)2{(CH2)3OC(O)C6H4R}(py)] (R = H, o-, m-or p-OCH3, p-OC7H15 or p-OC9H19) have been synthesized and fully characterized. The former series provides versatile precursor species for a wide range of polymethylene homo-and heteronuclear complexes, while the latter series confirms that, under mild conditions, elaboration from an ω-hydroxyl group can be achieved to generate stable metal complexes.
