186656-76-8

Basic information

• Product Name: 2-iodo-1-(4-methylbenzenesulfonyloxymethyl)benzene
• Synonyms: 2-iodo-1-(4-methylbenzenesulfonyloxymethyl)benzene
• CAS NO: 186656-76-8
• Molecular Weight: 388.226
• Mol File: 186656-76-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-iodo-1-(4-methylbenzenesulfonyloxymethyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 2-iodo-1-(4-methylbenzenesulfonyloxymethyl)benzene(186656-76-8)
• EPA Substance Registry System: 2-iodo-1-(4-methylbenzenesulfonyloxymethyl)benzene(186656-76-8)

Safety Data

• Hazardous Substances Data: 186656-76-8(Hazardous Substances Data)

Upstream product

• 5159-41-1 2-iodobenzyl alcohol 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 203112-98-5 6-(2-iodobenzyl)-2-methyl-5-(2-propene)-2-cyclohexen-1-one 
• 203112-84-9 6-(2-iodobenzyl)-2-cyclohexen-1-one 
• 4622-38-2 2-iodobenzyliodide 

Relevant articles and documents

Synthesis of biaryls via intramolecular free radical ipso-substitution reactions

A variety of functionalised biaryls and heterobiaryls are prepared by intramolecular free radical [1,5]-ipso-substitution using sulfonamide and sulfonate derived tethering chains. The overall efficiency of the process is determined by appropriately positioned substituents on the aromatic acceptor ring. The extension of the process to benzylic sulfonates and their corresponding N-methylsulfonamide alternatives as substrates in potential [1,6]-ipso-substitution reactions leads mainly to the alternative [1,7] addition products.

A new route to the synthesis of bicyclo [3.3.2] nonene by radical cyclisation

Radical-induced cyclisation to form 7-membered ring with bicyclic framework was achieved by tributyltin hydride (TBTH) and α, α'-azobis- (isobutyronitrile) (AIBN).