18677-34-4

Basic information

• Product Name: benzhydryltriethylsilane
• Synonyms: benzhydryltriethylsilane
• CAS NO: 18677-34-4
• Molecular Weight: 282.501
• Mol File: 18677-34-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: benzhydryltriethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: benzhydryltriethylsilane(18677-34-4)
• EPA Substance Registry System: benzhydryltriethylsilane(18677-34-4)

Safety Data

• Hazardous Substances Data: 18677-34-4(Hazardous Substances Data)

Upstream product

• 617-86-7 triethylsilane 
• 4545-20-4 benzophenone tosylhydrazone 
• 119-61-9 benzophenone 
• 745783-97-5 triethyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane 
• 58241-12-6 phenyl 2,2-diphenylacetate 

Relevant articles and documents

Palladium(0)-catalyzed C(sp3)-Si bond formation: Via formal carbene insertion into a Si-H bond

Pd(0)-Catalyzed formal carbene insertion into Si-H bonds has been achieved as an efficient method for C(sp3)-Si bond formation. The reaction, which uses readily available N-tosylhydrazones as the diazo precursors, is highly efficient and shows a wide substrate scope. Rh(ii) and Cu(i) salts, which are the widely used catalysts for carbene insertion reactions, have been proved to be ineffective for the current reaction. A Pd(ii) carbene migratory insertion/reductive elimination mechanism is proposed.

Decarbonylative Silylation of Esters by Combined Nickel and Copper Catalysis for the Synthesis of Arylsilanes and Heteroarylsilanes

An efficient nickel/copper-catalyzed decarbonylative silylation reaction of carboxylic acid esters with silylboranes is described. This reaction provides access to structurally diverse silanes with high efficiency and excellent functional-group tolerance