186805-17-4Relevant academic research and scientific papers
Syntheses and properties of some new tris(fluorophenyl)antimony and -bismuth compounds. Crystal structure of tris(2,6-difluorophenyl)bismuth
Lewe,Naumann,Nowicki,Schneider,Tyrra,Gilles,Tebbe
, p. 2009 - 2015 (1996)
(2,6-F2C6H3)3Bi, (2,4,6-F3C6H2)3Bi, and (2,6-F2C6H3)3Sb are prepared via Grignard reactions with BiBr3 and SbBr3, respectively. The syntheses and properties of the new compounds and the crystal structure of (2,6-F2C6H3)3Bi are described. From the reaction of BiBr3 with Ag(OCOC6H3F2) the bismuth benzoate Bi(OCOC6H3F2)3 is formed in 83% yield. Attempts to prepare (2,6-F2C6H3)3Bi by decarboxylation of the bismuth benzoate failed. Johann Ambrosius Barth 1996.
