186960-89-4

Upstream product

• 186960-88-3 (1'S,6'S)-3-(6'-benzyloxymethyl-2'-cyclohexenyl)nitropropane 
• 186960-87-2 (1'S,6'S)-3-(6'-benzyloxymethyl-2'-cyclohexenyl)-1-nitro-2-propanol 
• 186960-86-1 (1'S,6'S)-(6'-benzyloxymethyl-2'-cyclohexenyl)acetaldehyde 
• 178945-61-4 (1'S,6'S)-2-(6'-benzyloxymethyl-2'-cyclohexenyl)ethanol 

Downstream Products

• 186960-90-7 (3aR,4S,7aR)-4-benzyloxymethyl-7-hydroxy-3a,4,5,6,7,7a-hexahydroindan-1-one 
• 186960-91-8 (3aR,4S)-4-benzyloxymethyl-3a,4,5,6-tetrahydroindan-1-one 

Relevant academic research and scientific papers

INOC reaction in alkaloid synthesis-stereocontrolled formal total synthesis of (+)-pumiliotoxin C

A formal total synthesis of (+)-pumiliotoxin C (1), the antipode of the arrow poison frog toxin, starting from the chirally homogeneous (1'S, 6'S)-2-(6'-benzyloxymethyl-2'-cyclohexyl)ethanol (2) is described. The synthesis features the intramolecular nitr