186983-13-1

Basic information

• Product Name: Ir(H)(η(2)-CH2CMe2P(t)BuPh)(F)(P(t)Bu2Ph)
• CAS NO: 186983-13-1
• Molecular Weight: 655.839
• Mol File: 186983-13-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ir(H)(η(2)-CH2CMe2P(t)BuPh)(F)(P(t)Bu2Ph)(CAS DataBase Reference)
• NIST Chemistry Reference: Ir(H)(η(2)-CH2CMe2P(t)BuPh)(F)(P(t)Bu2Ph)(186983-13-1)
• EPA Substance Registry System: Ir(H)(η(2)-CH2CMe2P(t)BuPh)(F)(P(t)Bu2Ph)(186983-13-1)

Safety Data

• Hazardous Substances Data: 186983-13-1(Hazardous Substances Data)

Upstream product

• 61663-64-7 Ir(H)2Cl(P(t)Bu₂Ph)2 
• 185250-10-6 Ir(H)2F(P(t)Bu₂Ph)2 

Relevant articles and documents

Fluoro-Ligand Promotion of C-H Activation

Ethylene dehydrogenates Ir(H)2FL2 (L = Jt-Bu2Ph) to give the metalated species 1 and 2. These metalated species catalyze the exchange of deuterium from C6D6 to ethylene, and to tBu and orthophenyl sites of coordinated L. This exchange is proposed to benefit from π-donation from F to Ir.