187031-80-7

Upstream product

• 144830-21-7 phenyl 2,3-di-O-benzyl-4,6-di-O-benzylidene-1-thio-β-D-galactopyranoside 
• 231623-55-5 phenyl 2,3-di-O-benzyl-1-thio-β-D-galactopyranoside 

Downstream Products

• 187031-83-0 (2S,3R,4S,5R,6S)-4,5-Bis-benzyloxy-3-(4-methoxy-benzyloxy)-6-phenylsulfanyl-tetrahydro-pyran-2-carboxylic acid tert-butyl ester 
• 187031-84-1 (2S,3R,4S,5R,6S)-4,5-Bis-benzyloxy-3-(4-methoxy-benzyloxy)-6-phenylsulfanyl-tetrahydro-pyran-2-carboxylic acid benzyl ester 
• 187031-93-2 C₆₁H₆₀O₁₃ 
• 187031-90-9 C₆₆H₇₀O₁₄ 
• 187031-92-1 C₆₉H₆₈O₁₄ 

Relevant academic research and scientific papers

Anchimeric assistance by the anomeric phenylthio group in the nucleophilic substitution of a 6-O-trifluoromethanesulfonyl-β-D-galactopyranoside

Nucleophilic displacement by the cyanide anion of the 6-O-triflyl group in phenyl 6-O-triflyl-2,3-di-O-benzyl-4-O-p-methoxybenzyl-1-thio-β-D-galactopyranoside takes place via an intermediate 1,6-sulfonium salt resulting from the anchimeric assistance of the C-1 phenylthio group. Copyright (C) 1999 Elsevier Science Ltd.

An efficient and highly stereoselective α(1 → 4) glycosylation between two D-galacturonic acid ester derivatives

The highly stereoselective α(1 → 4) coupling between two D-galacturonic acid ester derivatives was accomplished in good yields, for the first time, using a phenylthioglycoside as donor. The method was designed to prepare D-galacturonic acid oligomers with methyl ester groups in definite positions.