187034-16-8Relevant academic research and scientific papers
N-H insertion reactions of rhodium carbenoids. Part 2. Preparation of N-substituted amino(phosphoryl)acetates (N-substituted phosphorylglycine esters)
Ferris, Leigh,Haigh, David,Moody, Christopher J.
, p. 2885 - 2888 (1996)
Rhodium(II) acetate-catalysed reaction of ethyl 2-diazo-2-diethoxyphosphorylacetate 2 with carbamates, amides, ureas or anilines gives a range of N-substituted 2-amino-2-diethoxyphosphorylacetates 3-18 by N-H insertion reaction of the intermediate rhodium
Synthesis of N-aryl indole-2-carboxylates via an intramolecular palladium-catalysed annulation of didehydrophenylalanine derivatives
Brown, Julien A.
, p. 1623 - 1626 (2007/10/03)
Nitrogen substituted indole-2-carboxylates can be prepared via an intramolecular palladium-catalysed amination reaction of didehydrophenylalanine derivatives using PdCl2(dppf) and KOAc in DMF at 90°C to form the indole nucleus. The specific for
