187246-33-9Relevant academic research and scientific papers
NMR studies of chiral P,S-chelate platinum, rhodium, and iridium complexes and the x-ray structure of a palladium (II) allyl derivative
Albinati, Alberto,Eckert, Jürgen,Pregosin, Paul,Rüegger, Heinz,Salzmann, Renzo,St?ssel, Corinna
, p. 579 - 590 (2008/10/08)
Several Rh(I), Ir(III), and Pt(II) complexes of the chiral P,S-bidentate ligand 2 have been prepared and characterized. Detailed two-dimensional NMR studies show that (i) the boat-type chelate ring and the stereogenic sulfur center can invert rapidly at a
