18733-88-5Relevant academic research and scientific papers
Alkynylsilanes and alkynyl(vinyl)silanes. synthesis, molecular structures and multinuclear magnetic resonance study
Wrackmeyer, Bernd,Khan, Ezzat,Bayer, Stefan,Tok, Oleg L.,Klimkina, Elena V.,Milius, Wolfgang,Kempe, Rhett
experimental part, p. 725 - 744 (2011/01/11)
Alkynylsilanes bearing one to four alkynyl groups at silicon, with organyl groups (Me, Ph, Vin), H, Cl at silicon, and with substituents H, nBu, tBu, Ph, C6H4-4-Me, 3-thienyl, CH 2NMe2 at t
Reactivity of triethylborane towards di(alkyn-1-yl)(chloro)silanes. Competition between 1,1-organoboration and 1,2-hydroboration
Khan, Ezzat,Bayer, Stefan,Wrackmeyer, Bernd
experimental part, p. 47 - 57 (2009/05/08)
Reactions of di(alkyn-1-yl)(chloro)silanes, HSi(Cl)(C≡C-R) 2, R1Si(Cl)(C≡C-R)2 or HSi(Cl)-(C≡C-R) C≡C-R′, with an excess of triethylborane, BEt3, proceed slowly (several days) at 100 - 120 °C. Twofold 1,1-organoboration of
