187330-14-9

Basic information

• Product Name: 4-Oxo-pentanoic acid (2R,3S,4S,5R,6S)-2-benzyloxymethyl-6-methylsulfanyl-3,5-bis-(4-oxo-pentanoyloxy)-tetrahydro-pyran-4-yl ester
• Synonyms: 4-Oxo-pentanoic acid (2R,3S,4S,5R,6S)-2-benzyloxymethyl-6-methylsulfanyl-3,5-bis-(4-oxo-pentanoyloxy)-tetrahydro-pyran-4-yl ester
• CAS NO: 187330-14-9
• Molecular Weight: 594.68
• Mol File: 187330-14-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Oxo-pentanoic acid (2R,3S,4S,5R,6S)-2-benzyloxymethyl-6-methylsulfanyl-3,5-bis-(4-oxo-pentanoyloxy)-tetrahydro-pyran-4-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Oxo-pentanoic acid (2R,3S,4S,5R,6S)-2-benzyloxymethyl-6-methylsulfanyl-3,5-bis-(4-oxo-pentanoyloxy)-tetrahydro-pyran-4-yl ester(187330-14-9)
• EPA Substance Registry System: 4-Oxo-pentanoic acid (2R,3S,4S,5R,6S)-2-benzyloxymethyl-6-methylsulfanyl-3,5-bis-(4-oxo-pentanoyloxy)-tetrahydro-pyran-4-yl ester(187330-14-9)

Safety Data

• Hazardous Substances Data: 187330-14-9(Hazardous Substances Data)

Upstream product

• 40608-06-8 levulinic anhydride 

Downstream Products

• 187330-21-8 C₅₅H₆₄N₄O₂₀ 
• 187330-20-7 C₆₂H₆₈N₄O₂₀ 

Relevant articles and documents

A new strategy for stereoselective synthesis of sialic acid-containing glycopeptide fragment

Sialic acid donor 5, which has a thiophenyl group as a stereocontrolling auxiliary and thiomethyl group as a leaving group was prepared and subjected to model glycosylation. Reactions with acceptor substrates 6, 7, and 8 gave coupled products 9b, 10b, and 11b, respectively, in a higher efficiency than previously observed for the bromide 1a. This reaction was further applied to the synthesis of protected glyco-amino acid fragment 12, that is strategically designed for the synthesis of sialic acid containing glycopeptides.