187682-10-6Relevant articles and documents
Carbene-Catalyzed Reductive Coupling of Nitrobenzyl Bromide and Nitroalkene via the Single-Electron-Transfer (SET) Process and Formal 1,4-Addition
Wang, Yuhuang,Du, Yu,Huang, Xuan,Wu, Xingxing,Zhang, Yuexia,Yang, Song,Chi, Yonggui Robin
supporting information, p. 632 - 635 (2017/02/10)
A carbene-catalyzed reductive 1,4-addition of nitrobenzyl bromides to nitroalkenes is disclosed. The reaction proceeds via a carbene-enabled single-electron-transfer process that generates radicals as key intermediates. The present study expands the potentials of carbene catalysis and offers unusual transformations for common substrates in organic synthesis.
Dendrimers consisting of stilbene or distyrylbenzene building blocks synthesis and stability
Lehmann, Matthias,Schartel, Bernhard,Hennecke, Manfred,Meier, Herbert
, p. 13377 - 13394 (2007/10/03)
On the basis of Wittig-Homer reactions and protection group techniques compound 7 for the core and the components 9a-c and 11a-c for the dendrons were prepared and linked in the final step. The convergent synthesis yielded constitutionally and configurationally pure dendrimers (2a-c, 2a'-c') which consist of distyrylbenzene units. Their thermo-oxidative stability in the presence of air was studied by chemiluminescence and compared to the dendrimers 1 consisting of stilbene units.