18780-03-5Relevant articles and documents
Pyrylium salts in the synthesis of redoxites
Dzaraeva,Sabanov, V. Kh.,Dzhatieva,Abaeva
, (2013)
Redoxites poly(2,6-diphenyl-4-vinylpyran), poly(2,6-diphenyl-4- vinylpyrylium perchlorate), poly-(2,6-diphenyl-4-vinylpyridine) and poly(2,2′,6,6′-tetraphenyl-γ,γ′-dipyridine) were obtained based on pyrylium salts. Poly(2,2′,6,6′-tetraphenyl- γ,γ′-dipyrid
Mono- and dinuclear osmium N,N′-di- and tetraphenylbipyridyls and extended bipyridyls. Synthesis, structure and electrochemistry
Esteruelas, Miguel A.,Fernandez, Israel,Gomez-Gallego, Mar,Martin-Ortiz, Mamen,Molina, Pedro,Olivan, Montserrat,Oton, Francisco,Sierra, Miguel A.,Valencia, Marta
supporting information, p. 3597 - 3608 (2013/03/28)
The efficient synthesis of mono- and dinuclear Os(iv) bipyridyl complexes is reported. These compounds show a two-step oxidation process leading to notable structural changes, which are reflected in their emission properties. During the second oxidation process a tetracation with a hydride-dihydrogen structure (instead of a trihydride) is formed. This results in a significant bathochromic shift of the emission band, accompanied by a moderate increase in intensity.