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DEHYDROCONDENSATION OF ORGANIC HYDROSILANES WITH SILANOLS. PART I. KINETICS AND MECHANISM OF THE REACTION IN DIMETHYLFORMAMIDE
Chrusciel, Jerzy,Lasocki, Zygmunt
, p. 113 - 120 (2007/10/02)
Kinetics of dehydrocondensation of organic hydrosilanes with silanols in DMF and in presence of zinc and cadmium halogenides has been studied.The reactivities of series of hydrosilanes and hydrosiloxanes were determined.Activation parameters of the reaction and catalytic activities of the catalysts were determined and shown to be consistent with the mechanism which had been earlier proposed basing on formal kinetics.
