187875-16-7

Basic information

• Product Name: (Z)-2-phenylethenyldisiamylborane
• Synonyms: (Z)-2-phenylethenyldisiamylborane
• CAS NO: 187875-16-7
• Molecular Weight: 256.239
• Mol File: 187875-16-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (Z)-2-phenylethenyldisiamylborane(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-2-phenylethenyldisiamylborane(187875-16-7)
• EPA Substance Registry System: (Z)-2-phenylethenyldisiamylborane(187875-16-7)

Safety Data

• Hazardous Substances Data: 187875-16-7(Hazardous Substances Data)

Upstream product

• 1069-54-1 bis-(1,2-dimethylpropyl)borane 
• 932-87-6 1-Bromo-2-phenylacetylene 
• 513-35-9 2-methyl-but-2-ene 
• 932-88-7 1-iodo-2-phenylethyne 
• 187874-76-6 ((Z)-1-Bromo-2-phenyl-vinyl)-bis-(1,2-dimethyl-propyl)-borane 

Downstream Products

• 97632-25-2 (Z)-penta-1,4-dien-1-ylbenzene 

Relevant articles and documents

Homo- and heterocoupling of terminal conjugated enynes: One-pot synthesis of alka-1,7-diene-3,5-diynes and alk-1-ene-3,5-diynes via two types of coupling reaction

Conjugated dienediynes and enediynes with definite geometry- have been prepared in a one-pot manner. This protocol involves two types of coupling reaction, a Suzuki-type coupling and either a Hay coupling or a Cadiot-Chodkiewicz coupling. Thus, the copper

Construction of terminal conjugated enynes: Cu-mediated cross-coupling reaction of alkenyldialkylborane with (trimethylsilyl)ethynyl bromide

The cross-coupling reaction of (E)- and (Z)-alk-1-enyldialkylborane with (trimethylsilyl)ethynyl bromide proceeds in the presence of a catalytic amount of copper(II) acetylacetonate and a base under extremely mild conditions to provide conjugated enynes w

Stereoselective dehalogenation of (Z)-1-halo-1-alkenyldialkylborane with tributyltin hydride: The behavior of tributyltin hydride as a hydride donor

The reaction of (Z)-1-halo-1-alkenyldialkylborane (1) with tributyltin hydride (n-Bu3SnH) at 0°C or room temperature results in reductive removal of the halogen atom to afford (E)- or (Z)-1-alkenyldialkylborane whose stereochemistry depends on the dialkylboryl group and the alkenyl group of 1.