187875-77-0Relevant academic research and scientific papers
Catalytic asymmetric [4 + 1] cycloaddition of vinylallenes with carbon monoxide: Reversal of the induced chirality by the choice of metal
Murakami, Masahiro,Itami, Kenichiro,Ito, Yoshihiko
, p. 4130 - 4135 (2007/10/03)
Rhodium(I) and platinum(0) complexes having a chiral ligand, 1,2-bis(2,5-dialkylphosphorano)-benzene, effected an asymmetric carbonylative [4 + 1] cycloaddition reaction of vinylallenes. Useful levels of asymmetric induction were attained even with substr
