1879-54-5Relevant academic research and scientific papers
THE REACTION OF BENZYLTRIPHENYLARSONIUM YLIDES WITH ALDEHYDES. A NOTE ABOUT THE MECHANISM OF THE WITTIG REACTION.
Broos, Rene,Anteunis, Marc J. O.
, p. 271 - 280 (2007/10/02)
The products and stereochemistry of the reaction of the benzyltriphenyl arsonium ylide with benzaldehyde and acetaldehyde both in the presence of lithium salts and under salt-free conditions are studied by 1H NMR at 360 MHz.The stereochemistry is discussed in view of recent developments in the mechanistic interpretation of the Wittig and Johnson-Corey-Chaykovsky reaction.
NEW PREPARATIONS OF p-NITROPHENYLCYCLOPROPANE
Broos, R.,Anteunis, M. J. O.
, p. 135 - 138 (2007/10/02)
The preparation of p-nitrocyclopropylbenzene by reaction of dimethyloxosulfonium methylide with p-nitrostyrene or p-nitrobenzyl iodide (bromide) in 67 and 37 percent yield respectively is reported.
