187940-11-0Relevant academic research and scientific papers
Generation and reaction of benzylammonium N-methylides with N-cyanomethyl or N-(ethoxycarbonylalkyl) groups
Zhang, Chen,Maeda, Yasuhiro,Shirai, Naohiro,Sato, Yoshiro
, p. 25 - 28 (1997)
N-Cyanomethyl-, N-ethoxycarbonylmethyl- and N-(3-ethoxycarbonylpropyl)-N-methylbenzylammonium N-methylides 6a,b and 22 have been generated by fluoride ion-induced desilylation of the corresponding N-(trimethylsilylmethyl)benzylammonium salts 5a,b and 21. Sommelet-Hauser 7, 23 and Stevens 8, 24 rearrangement products were obtained from 6a and 22, but not from 6b.
