187962-52-3

Upstream product

• 58479-61-1 tert-butylchlorodiphenylsilane 
• 187962-49-8 4(R)-(4(R)-methoxy-3(R),5(R)-dimethyltetrahydrofuran-2(S)-yl)-2(S)-methylpentane-1,4-diol 
• 187962-45-4 {(2R,5S,6S)-5-Methyl-6-[(E)-(5S,7S)-3,4,7-trihydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-oct-1-enyl]-tetrahydro-pyran-2-yl}-acetic acid methyl ester 
• 187962-43-2 {(2R,5S,6S)-6-[(1E,3E)-(5S,7S)-7-Hydroxy-7-((2S,3R,4R,5R)-4-methoxy-3,5-dimethyl-tetrahydro-furan-2-yl)-1,5-dimethyl-octa-1,3-dienyl]-5-methyl-tetrahydro-pyran-2-yl}-acetic acid methyl ester 
• 187962-44-3 methyl 2-((2R,5S,6S)-6-((S,2E,4E)-7-((2R,3R)-3-((2R,3R,4R)-4-hydroxy-3-methoxypentan-2-yl)-2-methyloxiran-2-yl)-6-methylhepta-2,4-dien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetate 
• 142861-00-5 2-((2R,5S,6S)-6-((S,2E,4E)-7-((2R,3R)-3-((2R,3R,4R)-4-hydroxy-3-methoxypentan-2-yl)-2-methyloxiran-2-yl)-6-methylhepta-2,4-dien-2-yl)-5-methyltetrahydro-2H-pyran-2-yl)acetic acid 

Relevant academic research and scientific papers

Herboxidiene: Determination of absolute configuration by degradation and synthetic studies

Degradation of the novel polyketide herbicide herboxidiene leads to useful fragments for further analogue synthesis and also enabled determination of the absolute configuration of the natural product via asymmetric synthesis of the respective fragments.