188002-55-3Relevant academic research and scientific papers
Efficient and selective oxidation of primary and secondary alcohols using an iron(III)/phenanthroline complex: Structural studies and catalytic activity
Biswas, Bhaskar,Kole, Niranjan,Al-Hunaiti, Afnan,Raeisaenen, Minna T.,Ansalone, Simone,Leskelae, Markku,Repo, Timo,Chen, Yen-Tung,Tsai, Hui-Lien,Naik, Anil D.,Railliet, Antoine P.,Garcia, Yann,Ghosh, Rajarshi
, p. 4479 - 4485,7 (2020/08/24)
An efficient catalytic system for the oxidation of alcohols has been developed by using iron(III) catalyst [Fe(phen)2Cl 2]NO3 (1) (phen = 1,10-phenanthroline) and H 2O2 as terminal oxidant. A series of primary and secondary alcohols were oxidized into aldehydes and ketones in good yields and excellent selectivities after a short reaction time. The mononuclear iron(III) complex [Fe(phen)2Cl2]NO3 was characterized by several independent methods. The X-ray structure shows distorted octahedral geometry around the FeIII center, which is in a high-spin state (S = 5/2) according to Moessbauer study. Copyright
FACILE HOMOGENEOUS HYDROGENATIONS OF HINDERED OLEFINS WITH PF6
Suggs, J. William,Cox. S. D.,Crabtree, Robert H.,Quirk, Jennifer M.
, p. 303 - 306 (2007/10/02)
The title complex readily hydrogenates a number of hindered steroidal olefin groups from the α face, without reducing ketone carbonyl groups, carbon-halogen bonds or cyclopropane rings.
