188014-77-9

Upstream product

• 188014-76-8 2-(tert-Butyl-dimethyl-silanyloxymethyl)-4-methyl-1-(2-methyl-1-triisopropylsilanyloxy-allyl)-benzene 
• 188014-74-6 [5-Methyl-2-(2-methyl-1-triisopropylsilanyloxy-allyl)-phenyl]-methanol 
• 188014-73-5 1-[2-(tert-Butyl-dimethyl-silanyloxymethyl)-4-methyl-phenyl]-2-methyl-prop-2-en-1-ol 
• 188014-75-7 1-[2-(hydroxymethyl)-4-methylphenyl]-2-methyl-2-propen-1-ol 
• 587-03-1 3-methylbenzyl alcohol 
• 188014-80-4 5-Methyl-2-(2-methyl-1-triisopropylsilanyloxy-allyl)-benzaldehyde 

Downstream Products

• 188014-78-0 Triisopropyl-(1-{2-[(Z)-3-(4-methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-allyloxy)-silane 
• 188014-79-1 1-{2-[(Z)-3-(4-Methoxy-benzyloxymethyl)-1-methoxymethoxy-penta-2,4-dienyl]-4-methyl-phenyl}-2-methyl-prop-2-en-1-ol 

Relevant academic research and scientific papers

Planar tether control groups and π-facial selectivity: Intramolecular cycloadditions for polycyclic systems

The direct synthesis of the fused ring systems 11 (R = Me, H) and the decalin 14 are described. The use of a planar tether control group (either aromatic ring or double bond) greatly facilitates the key Diels-Alder cycloadditions. A second intermolecular cycloaddition of 14 with cyclopentadiene afforded the tetracyclic adduct 17. The interaction between the allylic ethers and diene subslituents influences the facial selectivity observed in these examples.