18822-13-4Relevant academic research and scientific papers
Synthesis and NMR characterization of a spirosilole tetra-anion: A homogeneous four-electron reductant
Han, Zhengang,Bai, Lei,Huo, Shuhui,Chen, Jing,Lu, Xiaoquan
, p. 103 - 108 (2018)
The development of highly selective homogeneous electron transfer reagents is highly desirable for synthetic chemistry. An isolable spirosilole tetra-anion described in this paper has been proved to be a promising soluble electron transfer reagent. The re
Silole Silylene Route to NHC-Stabilized Fused 1-Silabicycles and 1,1′-Spirobisiloles
Li, Tianhao,Zhang, Jianying,Cui, Chunming
, p. 1218 - 1223 (2017)
The reaction of an NHC-stabilized silole silylene (1, 1-silacyclopentadienylidene) with one equivalent of internal acetylenes resulted in the formation of NHC-stabilized 1-silabicyclo[3.2.0]hepta-1,3,6-trienes, which subsequently reacted with one equivale
Four-electron homogeneous reducing agent, preparation method and applications thereof
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Paragraph 0050-0051, (2020/01/12)
The invention discloses a 2,3,4,5,2',3',4',5'-octaaryl spiro silole four-anion compound with a structure represented by a formula (I), wherein Ar is C6-C10 aryl or substituted aryl, preferably one selected from phenyl, 2,6-dimethyl phenyl and 2,6-diisopro
Molecular optical switches: Synthesis, structure, and photoluminescence of spirosila compounds
Yan, Duanchao,Mohsseni-Ala, Javad,Auner, Norbert,Bolte, Michael,Bats, Jan W.
, p. 7204 - 7214 (2008/03/12)
Starting from a silicon dichloro substituted silole and a silacyclobutene, a series of new organosilicon-based spiro compounds was synthesized by using standard organometallic reaction procedures. The spiro compounds that combine two organic photoactive s
