188256-80-6Relevant academic research and scientific papers
Electrochemical activation of nucleophilic substitution in aryl and vinyl halides with [CpFe(CO)2]- anion using homogeneous redox-catalysis
Magdesieva,Kukhareva,Shaposhnikova,Artamkina,Beletskaya,Butin
, p. 51 - 58 (1996)
The feasibility of indirect electrochemical activation of nucleophilic substitution in several non-active aryl and vinyl halides with [CpFe(CO)2]- by means of a specially introduced mediator (a reversible redox couple A/A·-) has been demonstrated. The efficiency of different mediators for several aryl and vinyl halides as well as the corresponding σ-aryl and σ-vinyl derivatives of (η5-cyclopentadienyl)irondicarbonyl has been examined. It was shown that by carefully selecting the mediator it becomes possible to perform the electrochemically induced substitution reaction even in those cases where the substitution products are reduced irreversibly and at less cathodic potentials than the initial substrates.
Nucleophilic addition to the η2-alkyne ligand in [CpFe(CO)2(η2-R-C≡C-R)]+. Dependence of the alkenyl product stereochemistry on the basicity of the nucleophile
Akita, Munetaka,Kakuta, Satoshi,Sugimoto, Shuichiro,Terada, Masako,Tanaka, Masako,Moro-oka, Yoshihiko
, p. 2736 - 2750 (2008/10/08)
Reaction of the cationic η2-alkyne iron complex, [Fp(η2-Ph-C≡CPh)]BF4 (1) [Fp = (η5-C5H5)Fe(CO)2], with various O-, N-, and C-nucleophiles afforded products containing the Ph-C=C
