188296-15-3

Basic information

• Product Name: [Cr(CO)3(C₆H₅CH(C₆H₅)CH(CO₂CH₃)NHCO₂C(CH₃)3)]
• CAS NO: 188296-15-3
• Molecular Weight: 491.461
• Mol File: 188296-15-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Cr(CO)3(C₆H₅CH(C₆H₅)CH(CO₂CH₃)NHCO₂C(CH₃)3)](CAS DataBase Reference)
• NIST Chemistry Reference: [Cr(CO)3(C₆H₅CH(C₆H₅)CH(CO₂CH₃)NHCO₂C(CH₃)3)](188296-15-3)
• EPA Substance Registry System: [Cr(CO)3(C₆H₅CH(C₆H₅)CH(CO₂CH₃)NHCO₂C(CH₃)3)](188296-15-3)

Safety Data

• Hazardous Substances Data: 188296-15-3(Hazardous Substances Data)

Upstream product

• 32825-32-4 diphenylmethane tricarbonylchromium 
• 138219-39-3 2-bromo-2-(N-tert-butoxycarbonylamino)acetic acid methyl ester 

Relevant articles and documents

Introduction of organometallic fragments into α-amino acids by reactions of α-bromoglycine derivatives with anionic organotransition-metal compounds

The reactions of protected cc-bromoglycine esters R'lOlCNHCHtBrJCO2R2 (R1 = Ph, OCMe3; R2 = Me, JBu) with organometallic anions of acetylferrocene, CpFe(CO)(PPh3)-C(O)CH3, (OC)5M=C(OMe)CH3 (M = Cr, W), (OC)3Cr(η6-diphenylmethane), (OC)3Cr(η6-fluorene), (OC)3Cr(η6-dihydroanthracene) and of (OC)3Cr(η6-aniline) and (OC)3Cr(η6-o-toluidine) provide a method for the introduction of organometallic fragments into the side chains of α-amino acids. The complexes may be useful as markers for α-amino acids in peptides. The compound (OC)3Cr(η6-o-C6H4(CH 3)NHC-(H)(CO2Me)NHC(O)Ph was characterized by X-ray diffraction. VCH Verlaegsgesellschaft mbH,.