18833-49-3Relevant academic research and scientific papers
A novel synthesis of quinoline-4(1H)-thiones by thermolysis of enaminothioesters.
Moussounga, Jacques Emmanuel,Bouquant, James,Chuche, Josselin
, p. 249 - 258 (2007/10/02)
A novel synthesis producing good yields of quinoline-4(1H)-thiones and involving the flow vacuum pyrolysis of enaminothioesters has been developed.The results are discussed in terms of the intermediate formation of iminothioketenes, whose electrocyclization leads to the title compounds. - Key words: β-oxoditioester / β-oxothionoester / N-phenylenaminodithioester / N-phenylenaminothionoester / quinoline-4(1H)thione / flow thermolysis
