1884-29-3

Basic information

• Product Name: ethyl 3-bromo-3-phenylpropanoate
• CAS NO: 1884-29-3
• Molecular Formula: C₁₁H₁₃BrO₂
• Molecular Weight: 257.1237
• Mol File: 1884-29-3.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 283.2°C at 760 mmHg
• Flash Point: 125.1°C
• Density: 1.359g/cm³
• Vapor Pressure: 0.0032mmHg at 25°C
• Refractive Index: 1.538
• CAS DataBase Reference: ethyl 3-bromo-3-phenylpropanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 3-bromo-3-phenylpropanoate(1884-29-3)
• EPA Substance Registry System: ethyl 3-bromo-3-phenylpropanoate(1884-29-3)

Safety Data

• Hazardous Substances Data: 1884-29-3(Hazardous Substances Data)

Upstream product

• 64-17-5 ethanol 
• 4192-77-2 ethyl cinnamate 
• 103-36-6 ethyl 3-phenyl-2-propenoate 

Downstream Products

• 79912-78-0 diethyl 3,4-diphenylhexanedioate 
• 100075-04-5 (Z)-5-benzylidene-4-ethoxycarbonylmethoxy-3-phenylfuran-2(5H)-one 
• 100075-02-3 (Z)-4-benzoyloxy-5-benzylidene-3-phenylfuran-2(5H)-one 
• 100075-01-2 (Z)-5-benzylidene-3-phenyl-4-pivaloyloxyfuran-2(5H)-one 
• 100075-00-1 (Z)-5-benzylidene-4-isobutyryloxy-3-phenylfuran-2(5H)-one 
• 100075-03-4 (Z)-5-benzylidene-4-allyloxy-3-phenylfuran-2(5H)-one 
• 131146-32-2 4-methoxy-3-phenyl-5-(phenylmethyl)furan-2(5H)-one 
• 100074-81-5 (Z)-4-acetoxy-5-benzylidene-3-phenylfuran-2(5H)-one 
• 100074-92-8 4-methoxy-3-phenyl-5-(phenylmethylene)furan-2(5H)-one 
• 74026-71-4 4-hydroxy-3-phenyl-5-(phenylmethyl)furan-2(5H)-one 
• 78376-10-0 (Z)-5-benzylidene-4-hydroxy-3-phenylfuran-2(5H)-one 
• 2021-28-5 ethyl dihydrocinnamate 
• 37488-40-7 benzylamine hydrobromide 
• 4192-77-2 ethyl cinnamate 

Relevant articles and documents

A General Approach to Deboronative Radical Chain Reactions with Pinacol Alkylboronic Esters

The generation of carbon-centered radicals from air-sensitive organoboron compounds through nucleohomolytic substitution at boron is a general method to generate non-functionalized and functionalized radicals. Due to their reduced Lewis acidity, alkylboronic pinacol esters are not suitable substrates. We report their in situ conversion into alkylboronic catechol esters by boron-transesterification with a substoichiometric amount of catechol methyl borate combined with an array of radical chain processes. This simple one-pot radical-chain deboronative method enables the conversion of pinacol boronic esters into iodides, bromides, chlorides, and thioethers. The process is also suitable the formation of nitriles and allylated compounds through C?C bond formation using sulfonyl radical traps. The power of combining radical and classical boron chemistry is illustrated with a modular 5-membered ring formation using a combination of three-component coupling and protodeboronative cyclization.

A CONTRIBUTION TO MECHANISM OF ADDITION OF HYDROGEN BROMIDE TO THE α,β-UNSATURATEDSYSTEM OF 3-PHENYL-2-PROPENOIC ACID

Rate of addition of hydrogen bromide to meta- and para-substituted 3-phenyl-2-propenoic acids I was followed by polarography and UV spectroscopy.Rate of protonation either is the overall rate determining step or is at least comparable with the rate of the subsequent nucleophile attack.